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Austenite
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This phase is only possible in carbon steel at high temperature. It has a
Face Centre Cubic (F.C.C) atomic structure which can contain up to 2% carbon in
solution.
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Ferrite
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This phase has a Body Centre Cubic structure (B.C.C)
which can hold very little carbon; typically 0.0001% at room temperature.
It can exist as either: alpha or delta ferrite.
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Cementite
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Unlike ferrite and austenite, cementite is a very
hard intermetallic compound consisting of 6.7% carbon and the remainder iron,
its chemical symbol is Fe3C. Cementite is very hard, but when
mixed with soft ferrite layers its averidge hardness is reduced considerably.
Slow cooling gives course perlite; soft easy to machine but poor toughness.
Faster cooling gives very fine layers of ferrite and cementite; harder and
tougher
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Pearlite
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A mixture of alternate strips of ferrite and
cementite in a single grain. The distance between the plates and their
thickness is dependant on the cooling rate of the material; fast
cooling creates thin plates that are close together and slow cooling creates
a much coarser structure possessing less toughness. The name for this
structure is derived from its mother of pearl appearance under a microscope.
A fully pearlitic structure occurs at 0.8% Carbon. Further increases
in carbon will create cementite at the grain boundaries, which will start to
weaken the steel.
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Martensite
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If steel is cooled rapidly from austenite, the
F.C.C structure rapidly changes to B.C.C leaving insufficient time for the
carbon to form pearlite. This results in a distorted structure that has
the appearance of fine needles. There is no partial transformation associated
with martensite, it either forms or it doesnt. However, only the parts
of a section that cool fast enough will form martensite; in a thick section it
will only form to a certain depth, and if the shape is complex it may only
form in small pockets. The hardness of martensite is solely dependant on
carbon content, it is normally very high, unless the carbon content is
exceptionally low.
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